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MEASUREMENT OF FORMAL POTENTIALS FOR HYPERICIN IN DIMETHYLSULFOXIDE
Author(s) -
Redepenning Jody,
Tao Nengbing
Publication year - 1993
Publication title -
photochemistry and photobiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.818
H-Index - 131
eISSN - 1751-1097
pISSN - 0031-8655
DOI - 10.1111/j.1751-1097.1993.tb04927.x
Subject(s) - hypericin , oxidizing agent , cyclic voltammetry , photochemistry , excited state , chemistry , visible spectrum , electrochemistry , materials science , organic chemistry , physics , optoelectronics , electrode , atomic physics , biology , pharmacology
The formal potentials for hypericin are measured in dimethylsulfoxide using cyclic voltammetry. Two reversible one‐electron reductions and a more poorly defined multielectron oxidation are observed. The formal potentials for these processes are consistent with the visible spectrum of hypericin and they indicated that hypericin is both a good oxidizing agent and a good reducing agent in the excited state.

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