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REINVESTIGATION OF THE PHOTOPHYSICS OF 2‐(2′‐HYDROXY‐4′‐DIETHYLAMINOPHENYL)BENZOTHIAZOLE
Author(s) -
Chou PiTai,
Martinez Marty L.
Publication year - 1993
Publication title -
photochemistry and photobiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.818
H-Index - 131
eISSN - 1751-1097
pISSN - 0031-8655
DOI - 10.1111/j.1751-1097.1993.tb02922.x
Subject(s) - tautomer , benzothiazole , chemistry , intramolecular force , enol , photochemistry , excited state , fluorescence , proton , keto–enol tautomerism , singlet state , atomic physics , stereochemistry , organic chemistry , physics , quantum mechanics , catalysis
— The photophysical properties of 2‐(2′‐hydroxy‐4′‐diethylaminophenyl) benzothiazole (HABT) have been investigated by steady‐state and time‐resolved spectroscopies. In n‐heptane HABT exhibits both normal and tautomer emissions with ∼equal fluorescence intensity at room temperature, in contrast to a previous report in which negligible tautomer emission was observed. The normal/tautomer (400/500 nm) ratio of emission intensity increases as the temperature decreases. Two possible excited‐state intramolecular proton transfer (ESIPT) mechanisms are proposed, which cannot be resolved at the present stage. One proposed mechanism incorporates state mixing between ‐OH and ‐N(C 2 H 5 ) 2 charge transfer states, resulting in a significant energy barrier for ESIPT. An alternative mechanism is also proposed in which fast proton tunneling may take place between enol and keto forms, which are in equilibrium in the excited singlet state.