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SYNTHESIS OF DOUBLY AND MULTIPLY ISOTOPICALLY LABELED RETINALS
Author(s) -
Groesbeek M.,
Lugtenburg J.
Publication year - 1992
Publication title -
photochemistry and photobiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.818
H-Index - 131
eISSN - 1751-1097
pISSN - 0031-8655
DOI - 10.1111/j.1751-1097.1992.tb09711.x
Subject(s) - conjugated system , chemistry , chain (unit) , carotenoid , stereochemistry , combinatorial chemistry , organic chemistry , biochemistry , physics , astronomy , polymer
— In this paper a consecutive synthetic scheme is described that allows the synthesis of multiply 13 C labeled retinals with labels in the conjugated chain. This scheme can be extended to incorporation of 2 H labels in the conjugated chain. Also carotenoids can be multiply 13 C labeled with this strategy. The same approach has been used to label amino acids.