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SINGLET AND TRIPLET ENERGY TRANSFER IN α‐DIKETONE DERIVATIVES OF URACIL and THYMINE
Author(s) -
Lee Y.J.,
Burr J. G.
Publication year - 1983
Publication title -
photochemistry and photobiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.818
H-Index - 131
eISSN - 1751-1097
pISSN - 0031-8655
DOI - 10.1111/j.1751-1097.1983.tb04489.x
Subject(s) - phosphorescence , photochemistry , intersystem crossing , chromophore , chemistry , thymine , quantum yield , excited state , triplet state , singlet state , fluorescence , atomic physics , molecule , organic chemistry , physics , optics , dna , biochemistry
Irradiation of 1‐(3,4‐dioxopentyl)uracil (UPD) and 1‐(3.4‐dioxopentyl)thymine (TPD) in acetonitrile solution at 25°C, at the wavelength (280 nm) where only the pyrimidine absorbs the light, sensitizes both fluorescence and phosphorescence of the diketone chromophore in the sidechain. From comparison of the intensity in the corrected excitation spectra with the absorption spectra in acetonitrile solution, it was estimated that the yield of singlet energy transfer in UPD was 0.17 and in TPD was 0.44. It was also observed that the ratio of phosphorescence to fluorescence was greater in the sensitized emission than in that from direct excitation of the diketone chromophore. The yield of triplet energy transfer thus measured corresponds to minimum values for the yields of intersystem crossing from singlet excited state to triplet excited state of 0.075 in the uracil chromophore of UPD and of 0.14 in the thymine chromophore of TPD. These are in agreement with other recent values for these quantities. The value of this type of system as an intramolecular triplet counter is discussed.