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EVIDENCE FOR ELECTROPHILIC CHARACTER IN OXYGEN ATOM TRANSFER BY CARBONYL OXIDES
Author(s) -
Agarwal Sudhir K.,
Murray Robert W.
Publication year - 1982
Publication title -
photochemistry and photobiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.818
H-Index - 131
eISSN - 1751-1097
pISSN - 0031-8655
DOI - 10.1111/j.1751-1097.1982.tb03807.x
Subject(s) - electrophile , naphthalene , singlet oxygen , character (mathematics) , chemistry , oxygen atom , photochemistry , oxygen , singlet state , atom (system on chip) , medicinal chemistry , organic chemistry , molecule , catalysis , excited state , physics , geometry , mathematics , computer science , nuclear physics , embedded system
— Naphthalene was oxidized by carbonyi oxides produced by singlet oxygen oxidation of p, p‐ disubstituted diphenyldiazomethanes. Yields of naphthol products correlate with Hammett σ constants giving ρ=+0.93. The results are interpreted as indicating the electrophilic character of these oxidations.