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pH DEPENDENCE OF SENSITIZED PHOTOOXIDATION IN MICELLAR ANIONIC AND CATIONIC SURFACTANTS, USING THIAZINES DYES
Author(s) -
Bagno O.,
Soulignac J. C.,
JoussotDubien J.
Publication year - 1979
Publication title -
photochemistry and photobiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.818
H-Index - 131
eISSN - 1751-1097
pISSN - 0031-8655
DOI - 10.1111/j.1751-1097.1979.tb07823.x
Subject(s) - cationic polymerization , chemistry , protonation , photochemistry , adsorption , kinetics , inorganic chemistry , organic chemistry , ion , physics , quantum mechanics
— Our study of the kinetics of sensitized photooxidation, as a function of pH in anionic micellar systems using cationic dyes as sensitizers, shows that adsorption of the dye slows the protonation step of his triplet state. This observation has important implicaticins in interpretation of results in the so‐called photodynamic effect in biological systems: using cationic dyes as sensitizers the rate of photooxidation for the same pH is different depending whether or not the medium allows adsorption of the dye.