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INTERMEDIATES IN THE PHOTOLYSIS OF INDOLE: ROOM TEMPERATURE AQUEOUS SOLUTIONS AND LOW TEMPERATURE GLASSES
Author(s) -
Arce R.,
Grimison A.,
Revuelta J.,
Simpson G. A.
Publication year - 1975
Publication title -
photochemistry and photobiology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.818
H-Index - 131
eISSN - 1751-1097
pISSN - 0031-8655
DOI - 10.1111/j.1751-1097.1975.tb06695.x
Subject(s) - photodissociation , flash photolysis , indole test , photochemistry , aqueous solution , chemistry , absorption (acoustics) , kinetics , materials science , organic chemistry , reaction rate constant , physics , quantum mechanics , composite material
— Flash photolysis of indole aqueous solutions produces four transients with absorption maxima, in their order of appearance in time, at 720, 370, 380 and 520 nm. These correlate with low temperature photolysis observations. The results are interpreted in terms of electron‐radical cation generation and subsequent production of the indolyl radical.