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Construction and Testing of a Durable Platinum Wire Eh Electrode for In Situ Redox Measurements in the Subsurface
Author(s) -
Swerhone G. D. W.,
Lawrence J. R.,
Richards J. G.,
Hendry M. J.
Publication year - 1999
Publication title -
groundwater monitoring and remediation
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.677
H-Index - 47
eISSN - 1745-6592
pISSN - 1069-3629
DOI - 10.1111/j.1745-6592.1999.tb00214.x
Subject(s) - electrode , platinum , materials science , corrosion , dissolution , composite material , anoxic waters , in situ , reference electrode , metallurgy , electrochemistry , chemistry , chemical engineering , engineering , biochemistry , catalysis , organic chemistry , environmental chemistry
We have developed a rugged, durable platinum wire Eh electrode for application in subsurface environments. The electrode design is described in detail and its performance under aerobic and anaerobic steady‐state and transient conditions is assessed. The electrode consists of a 0.5‐mm‐diameter platinum wire (99.99% purity) cast in a glass fiber‐reinforced epoxy jacket. The construction allowed installation through direct insertion into sandy media to depths up to several meters. Data collection was through connection to a datalogger with high impedance input; data points were collected every 10 seconds and averaged and stored once an hour. The electrodes functioned in situ for periods of more than three years and gave reliable readings during oxic, anoxic, and transitional conditions. Performance testing and examination of electrodes recovered after three years in situ indicated that they were not impacted by corrosion, dissolution, or poisoning.