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Residual Diesel Measurement in Sand Columns After Surfactant/Alcohol Washing
Author(s) -
Martel Richard,
Gélinas Pierre J.
Publication year - 1996
Publication title -
groundwater
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.84
H-Index - 94
eISSN - 1745-6584
pISSN - 0017-467X
DOI - 10.1111/j.1745-6584.1996.tb01876.x
Subject(s) - diesel fuel , residual oil , hydrocarbon , residual , pulmonary surfactant , dissolution , chromatography , chemistry , environmental science , pulp and paper industry , mathematics , biochemistry , organic chemistry , algorithm , engineering
A new simple gravimetric technique has been designed to determine residual oil saturation of complex hydrocarbon mixtures (e.g., diesel) in sand column experiments because reliable methods are lacking. The He/N 2 technique is based on drying of sand columns by circulating helium gas to drag oil droplets in a cold trap (liquid nitrogen). With this technique, residual diesel measurement can be performed easily immediately after alcohol/surfactant washing and in the same lab. For high residual diesel content in Ottawa sand (25 to 30 g/kg), the technique is much more accurate (± 2% or 600 mg/kg) than the standard analytical methods for the determination of mineral oil and grease. The average relative error on partial diesel dissolution in sand column estimated after alcohol/surfactant flooding (residual saturation of 10 to 15 g/kg) is as low as 5%. The precision of the He/N 2 technique is adequate to compare relative efficiency of washing solutions when partial extraction of residual oil in Ottawa sand columns is performed. However, this technique is not adapted for determination of traces of oil in sediment or for environmental control of contaminated soils. Each diesel determination by the He/N 2 technique costs less than 8 $US in chemical products (helium and liquid nitrogen). A simple laboratory drying setup can be built for less than 400 $US which makes this technique valuable for diesel analyses when a large number of tests are required.