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Hydrolytic stability of composite repair bond
Author(s) -
Papacchini Federica,
Toledano Manuel,
Monticelli Francesca,
Osorio Raquel,
Radovic Ivana,
Polimeni Antonella,
GarcíaGodoy Franklin,
Ferrari Marco
Publication year - 2007
Publication title -
european journal of oral sciences
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.802
H-Index - 93
eISSN - 1600-0722
pISSN - 0909-8836
DOI - 10.1111/j.1600-0722.2007.00475.x
Subject(s) - adhesive , silane , materials science , composite number , silver nitrate , composite material , penetration (warfare) , curing (chemistry) , thermal stability , bond strength , layer (electronics) , chemistry , nuclear chemistry , organic chemistry , operations research , engineering
The hydrolytic stability of composite repairs is a desirable property. In the present study, the composite repair microtensile bond strength, failure mode distribution, and nanoleakage occurrence before and after thermocycling were evaluated. Standardized, 1‐month‐old composite substrates were roughened, cleaned, and randomly assigned to seven groups according to the intermediate agent applied. Resin‐based, silane‐based, and combined silane/adhesive coupling agents were investigated. The same resin composite as the substrate was used for repair. For each group, repaired samples were wet stored for 24 h (37°C) or thermocycled (5,000 cycles, 5−55°C). Failure mode and silver nitrate penetration were examined by stereomicroscopy. Intermediate agent, experimental condition, and their interaction were significant factors. Hydrophobic flowable composites resulted in statistically higher repair strengths, lower occurrence of adhesive failures, and good quality interfacial coupling without any silver uptake in both conditions. Light‐curing, hydrophilic resin monomer‐based intermediate agents, although not affected by thermocycling, showed a more pronounced silver penetration. The composite repair strength of a self‐curing silane/adhesive agent was significantly affected by thermal stresses, despite the absence of silver uptake. A prehydrolized silane agent recorded the lowest repair strength, with minimal or no evidence of interfacial silver impregnation after thermocycling. In conclusion, flowability and hydrophobic nature can be considered important properties when selecting intermediate agents for composite repair.