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Thermal Conductivity of Al 2 O 3 –ZrO 2 Composite Ceramics
Author(s) -
Hostaša Jan,
Pabst Willi,
Matějíček Jiří
Publication year - 2011
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1551-2916.2011.04875.x
Subject(s) - thermal conductivity , thermal diffusivity , materials science , sintering , composite number , ceramic , porosity , cubic zirconia , relative density , mineralogy , composite material , analytical chemistry (journal) , chemistry , thermodynamics , physics , chromatography
The Al 2 O 3 –ZrO 2 composite ceramics were prepared by slip casting in plaster molds and sintering at 1350°C in air. The composition of prepared samples varied from pure alumina to doped zirconia (3 Y‐TZP ) with steps of 10 vol%. The relative density of the sintered samples varied from 94% to 98%, depending on the composition. Thermal diffusivity of sintered samples was measured by means of the xenon flash method at 100°C, 200°C, 400°C, 600°C, 800°C, and 1000°C and thermal conductivities were calculated based on measured bulk densities and specific heat data and finally corrected for porosity effects. As expected, the thermal conductivity decreased with increasing zirconia content, and in the case of samples with higher alumina content, it also decreased with increasing temperature. Effective thermal conductivities are close to the lower H ashin– S htrikman bound and the recently proposed sigmoidal average. Empirical relations were used to fit the dependence of effective thermal conductivity of Al 2 O 3 –ZrO 2 composite ceramics on both composition and temperature.