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Loss and Recovery of Transparency in Pressure‐Consolidated Lu 3 Al 5 O 12
Author(s) -
Rhodes William H.,
Wang Yimin,
Brecher Charles,
Gary Baldoni J.
Publication year - 2011
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1551-2916.2011.04832.x
Subject(s) - annealing (glass) , hot isostatic pressing , materials science , ceramic , transparent ceramics , porosity , stoichiometry , composite material , mineralogy , sintering , chemistry , organic chemistry
Pr ‐doped Lu 3 Al 5 O 12 ( LuAG ) transparent ceramic, a potential scintillator material, was fabricated by sinter/hot isostatic pressing ( HIP ). The specimens were subjected to various post‐densification heat treatments and the evolution of porosity and its relationship to transparency was monitored and studied. Annealing was necessary to remove discoloration and to restore stoichiometry, but when performed at too high a temperature it caused a severe decrease in transparency. Transparency was restored by re HIP ing, indicating that some nanometer‐size pores remained even after the original HIP cycle, which expanded in size during annealing and contracted again during re‐ HIP ing. Annealing at a lower temperature restored stoichiometry without serious transparency degradation, due to a favorable difference in diffusion rates for mass transfer and O 2 −diffusion. This phenomenon illustrates a fundamental difference between residual porosity in ceramics consolidated by pressureless and pressure‐assisted processes.