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Room‐Temperature Solid‐State Reaction Behavior, Hydrothermal Crystallization and Physical Characterization of NaRE(MoO 4 ) 2 , and Na 5 Lu(MoO 4 ) 4 Compounds
Author(s) -
Wu Jianhua,
Yan Bing
Publication year - 2010
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1551-2916.2010.03715.x
Subject(s) - crystallization , hydrothermal circulation , materials science , molybdate , context (archaeology) , melting point , hydrothermal synthesis , inorganic chemistry , chemical engineering , mineralogy , chemistry , metallurgy , geology , paleontology , engineering , composite material
In the context, a novel composite synthesis technology is engaged in the preparation of NaRE(MoO 4 ) 2 (RE=Y, La, Nd, Eu, Gd, Tb, Er, and Yb) and Na 5 Lu(MoO 4 ) 4 compounds, which involves a room‐temperature solid‐state reaction and hydrothermal crystallization process. The synthesis mechanism is predicted, indicating that higher temperature and moisture can speed up the reaction process and especially the existence of crystalline water molecules in the precursor is necessary for the solid‐state reaction at room temperature. It is found that different rare‐earth nitrate precursors present different reactivity to sodium molybdate at room temperature. The crystallization degree of the products after the room‐temperature solid‐state reaction depends on the melting point of rare‐earth nitrate precursors. The hydrothermal treatment is beneficial for the good crystallization of NaRE(MoO 4 ) 2 (RE=Y, La, Nd, Eu, Gd, Tb, Er, and Yb) and Na 5 Lu(MoO 4 ) 4 . Finally, the photoluminescent spectra for these NaRE(MoO 4 ) 2 :Eu 3+ (La, Gd, and Y) are studied, which depend on the species of rare‐earth ions.