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Mechanisms and Kinetics of the Hydrothermal Oxidation of Bulk Titanium Silicon Carbide
Author(s) -
Zhang Haibin,
Presser Volker,
Berthold Christoph,
Nickel Klaus Georg,
Wang Xin,
Raisch Christoph,
Chassé Thomas,
He Lingfeng,
Zhou Yanchun
Publication year - 2010
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1551-2916.2009.03570.x
Subject(s) - hydrothermal circulation , materials science , oxide , kinetics , titanium , chemical engineering , mineralogy , chemistry , metallurgy , physics , quantum mechanics , engineering
Hydrothermal oxidation of bulk Ti 3 SiC 2 in continuous water flow was studied at 500°–700°C under a hydrostatic pressure of 35 MPa. The oxidation was weak at 500°–600°C and accelerated at 700°C due to the formation of cracks in oxides. The kinetics obeyed a linear time‐law. Due to the high solubility of silica in hydrothermal water, the resulting oxide layers only consisted of titanium oxides and carbon. Besides general oxidation, two special modes are very likely present in current experiments: (1) preferential hydrothermal oxidation of lattice planes perpendicular to the c ‐axis inducing cleavage of grains and (2) uneven hydrothermal oxidation related to the occurrence of TiC and SiC impurity inclusions. Nonetheless the resistance against hydrothermal oxidation is remarkably high up to 700°C.