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SiO 2 /Fe 2 O 3 Mesoporous Composite Prepared With an Activated Carbon Template in Supercritical Carbon Dioxide
Author(s) -
Fan Haijuan,
Xu Qun,
Li Jinge,
Cao Yanxia
Publication year - 2006
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1551-2916.2006.01208.x
Subject(s) - mesoporous material , materials science , composite number , supercritical carbon dioxide , supercritical fluid , scanning electron microscope , chemical engineering , transmission electron microscopy , carbon fibers , activated carbon , composite material , nanotechnology , catalysis , chemistry , organic chemistry , adsorption , engineering
SiO 2 /Fe 2 O 3 mesoporous composites have been prepared with a nanoscale casting process using an activated carbon (AC) template in supercritical carbon dioxide (SC CO 2 ). The composite precursor and acetone solvent (for Fe 2 O 3 precursor) were dissolved in SC CO 2 , and then coated on the AC in the desired supercritical condition. After removal of the AC template by calcinations in air at 600°C, SiO 2 /Fe 2 O 3 mesoporous composite were obtained. Temperature, pressure, and composite precursor ratio effects were studied. Scanning electron microscopy result shows that the porous structure of AC template had been well replicated by the composite product. Transmission electron micrograph indicates that nano iron oxides were well dispersed in the composite product.