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Criteria for Flame‐Spray Synthesis of Hollow, Shell‐Like, or Inhomogeneous Oxides
Author(s) -
Jossen R.,
Pratsinis S. E.,
Stark W. J.,
Mädler L.
Publication year - 2005
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1551-2916.2005.00249.x
Subject(s) - tetraethyl orthosilicate , spinel , boiling point , chemical engineering , materials science , inorganic chemistry , oxide , decomposition , solvent , scanning electron microscope , melting point , chemistry , organic chemistry , nanotechnology , engineering , metallurgy , composite material
The influence of metal precursor and solvent composition on the morphology of SiO 2 , Bi 2 O 3 , and other oxide particles made by flame spray pyrolysis (FSP) was investigated. Silica precursors with boiling points T bp =299–548 K dissolved in xylene were used as well as different solvents ( T bp =308–557 K) with tetraethyl‐orthosilicate (TEOS) as the silica precursor. For Bi 2 O 3 , nonvolatile bismuth nitrate pentahydrate was dissolved in solvents with T bp =338–468 K. Product powders were characterized by nitrogen adsorption, X‐ray diffraction, and scanning and transmission electron microscopy. From these data as well as from the literature of FSP synthesis of Bi 2 O 3 , CeO 2 , MgO, ZnO, Fe 2 O 3 , Y 2 O 3 , Al 2 O 3 , and Mg–Al spinel, it is inferred that hollow/inhomogeneous particles are formed at low combustion enthalpy densities and when the solvent boiling point is comparable or smaller than the precursor melting or decomposition point.