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Dispersion of SiC in Aqueous Media with Al 2 O 3 and Y 2 O 3 as Sintering Additives
Author(s) -
Zhang Jingxian,
Iwasa Mikio,
Jiang Dongliang
Publication year - 2005
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1551-2916.2005.00193.x
Subject(s) - dispersant , sintering , citric acid , materials science , dispersion (optics) , chemical engineering , aqueous solution , microstructure , silicon carbide , slurry , viscosity , composite material , mineralogy , chemistry , organic chemistry , physics , optics , engineering
It has been well accepted that polyethylene imine (PEI) is an effective dispersant for silicon carbide (SiC) in aqueous media. However, after the addition of sintering additives (Al 2 O 3 and Y 2 O 3 ), this dispersing effect is reduced significantly. In this work, a second dispersant, citric acid, was used to resolve this problem. It was found that citric acid could decrease the slurry viscosity (without sintering additives) and enhance the PEI adsorption on SiC particle surface. The optimal amount of citric acid required to achieve a minimum viscosity for 55 vol% SiC suspensions was equal to ∼0.87 wt% (at pH ∼6.8). With the aid of citric acid, well‐stabilized SiC suspensions (containing sintering additives) were realized, which exhibited slight shear thinning rheologies. After tape casting and SPS sintering, dense SiC samples were obtained with a homogeneous fine‐crystalline microstructure. Results showed that citric acid was an effective dispersant for improving the dispersion of SiC particles containing sintering additives.