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Sonochemical Preparation of PbTiO 3 Fine Powders
Author(s) -
Wang Junzhong,
Hu Yuan,
Liu Jie,
Chen Zuyao
Publication year - 2005
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1551-2916.2004.00015.x
Subject(s) - thermogravimetric analysis , materials science , nucleation , differential thermal analysis , transmission electron microscopy , microstructure , titanate , homogenization (climate) , thermal analysis , sol gel , chemical engineering , diffraction , mineralogy , analytical chemistry (journal) , ceramic , composite material , thermal , chemistry , nanotechnology , chromatography , organic chemistry , optics , biodiversity , ecology , physics , meteorology , engineering , biology
The sonochemical preparation of PbTiO 3 fine powders with lead acetate trihydrate and tetrabutyl titanate as precursors is reported in this paper. Narrow size distribution (40–60 nm) of gel‐derived PbTiO 3 nanocrystallites at 520°C was revealed by transmission electron microscopy. The preparation processings with ultrasonic irradiation and a control test without ultrasonic irradiation for comparison were investigated. Results of phase evolution, microstructure, and thermal analysis of gels were characterized and discussed between the control test and the ultrasonic preparations. Acoustic cavitation exerted an important influence on nucleation, gelation, and homogenization of as‐prepared gel, which contributed to the evolution of the resulting gel on further heat treatment. The sonochemical gel was detected to crystallize at temperature, as low as about 410°C, which was confirmed by X‐ray powder diffraction and thermogravimetric analysis and differential thermal analysis (TGA–DTA).