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Local and regional differences in the chemical potential of water in amphibolite facies pelitic schists
Author(s) -
DICKENSON M.P.
Publication year - 1988
Publication title -
journal of metamorphic geology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.639
H-Index - 114
eISSN - 1525-1314
pISSN - 0263-4929
DOI - 10.1111/j.1525-1314.1988.tb00426.x
Subject(s) - outcrop , pelite , geology , schist , metamorphism , geochemistry , metamorphic facies , facies , mineral , metamorphic rock , mineralogy , geomorphology , chemistry , organic chemistry , structural basin
Mineral assemblages in different samples of amphibolite facies pelitic schists collected from two separate outcrops in the Moosilauke area, NH, record differences in the chemical potential of water during metamorphism. Mineralogical, petrological, and field relations indicate that mineral assemblages at both outcrops equilibrated at 520°C and 3.5–4.0 kbar. Thermodynamic analysis of the mineral assemblages demonstrates that maximum chemical potential differences at each outcrop were of the order of 150 calories, over distances of 10–20 m. The differences in the chemical potential of water recorded in both bed‐to‐bed and outcrop‐to‐outcrop relations are consistent with the following conclusions: (1) mineral assemblages on a specific outcrop did not equilibrate with an external reservoir of fluid of fixed composition, (2) the relatively small magnitude of the chemical potential differences suggests little or no infiltration of externally derived fluid, (3) these differences on the outcrop scale are probably related to initial compositional variations and the buffer capacity of the mineral assemblage, and (4) the different values of the chemical potential of water exhibited by the various mineral assemblages permits an understanding of the effects of variable μ H2O for amphibolite facies pelitic schists.