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Synthesis, spectral and dyeing properties of phenylazopyrazolone‐containing acylamide disperse dyes designed for poly(lactic acid)
Author(s) -
Cui Zhihua,
Wang Xidong,
Chen Weiguo,
Hu Enling,
Liu Kai
Publication year - 2012
Publication title -
coloration technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.297
H-Index - 49
eISSN - 1478-4408
pISSN - 1472-3581
DOI - 10.1111/j.1478-4408.2012.00376.x
Subject(s) - dyeing , lactic acid , chemistry , solvatochromism , sorption , moiety , acetone , acid dye , fourier transform infrared spectroscopy , nuclear chemistry , absorbance , dimethylformamide , polymer chemistry , organic chemistry , chemical engineering , chromatography , adsorption , molecule , genetics , solvent , bacteria , engineering , biology
A series of phenylazopyrazolone disperse dyes containing an acylamide moiety were synthesised from carboxyl‐containing acid dyes via chlorination and amidation with different sorts of amines. The structures of these new dyes were confirmed by Fourier Transform–infrared, proton nuclear magnetic resonance, mass spectroscopy and elemental analysis. Their solvatochromic properties in different solvents were also investigated and the absorbance spectra of the acylamide dyes in solution exhibited a red shift when dissolved in dimethylformamide, compared with acetone. Their dyeing behaviour, including dye sorption, colour build‐up and colour fastness properties on poly(lactic acid) fibres, was also determined, whereupon it was found that the tertiary acylamide dyes simultaneously exhibited high dye sorption and satisfactory colour build‐up and fastness properties on the poly(lactic acid) fabric.