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Synthesis and properties of some new blue‐emitting triazine derivatives of 2‐aminoterephthalic acid, containing a polymerisable group and stabiliser fragment
Author(s) -
Miladinova Polya M,
Konstantinova Temenushka N
Publication year - 2009
Publication title -
coloration technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.297
H-Index - 49
eISSN - 1478-4408
pISSN - 1472-3581
DOI - 10.1111/j.1478-4408.2009.00203.x
Subject(s) - stabiliser , triazine , chemistry , fluorescence , polymer , fragment (logic) , combinatorial chemistry , 1,3,5 triazine , organic chemistry , group (periodic table) , polymer chemistry , physics , food science , quantum mechanics , computer science , programming language
Seven new blue‐emitting triazine derivatives of 2‐aminoterephthalic acid were synthesised, two of which contained a polymerisable group, one a stabiliser fragment and two containing both a polymerisable group and a stabliser fragment. The synthesised compounds were characterised by analytical methods. The ability of four of the derivatives to copolymerise with methylmethacrylate was demonstrated, thus they can be used for obtaining polymers with a whiteness and fluorescence stable to solvents. Two of the compounds, containing a combination of a stabiliser fragment and a polymerisable group, can be used for ‘one‐step’ stabilisation and whitening of polymer materials. All the compounds, possessing an intense blueish fluorescence, are suitable as fluorescent whitening agents for textiles.