Premium
Kinetic data for the crosslinking reaction of polycarboxylic acids with cellulose
Author(s) -
Schramm C,
Rinderer B,
Bobleter O
Publication year - 1997
Publication title -
journal of the society of dyers and colourists
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.297
H-Index - 49
eISSN - 1478-4408
pISSN - 0037-9859
DOI - 10.1111/j.1478-4408.1997.tb01861.x
Subject(s) - chemistry , activation energy , citric acid , butane , cellulose , reaction rate constant , tricarboxylic acid , kinetic energy , arrhenius equation , organic chemistry , inorganic chemistry , kinetics , nuclear chemistry , catalysis , citric acid cycle , physics , quantum mechanics , enzyme
Kinetic data (rate constant, Arrhenius activation energy, frequency factor) of the esterification of polycarboxylic acids (butane‐1, 2, 3, 4‐tetracarboxylic acid, citric acid and pyromellitic acid) have been determined by means of isocratic HPLC measuring the portion of polycarboxylic acid that does not react with cellulosic material. The order of activation energy is as follows: citric acid > butane‐1, 2, 3, 4‐tetracarboxylic acid > pyromellitic acid.