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Morphology of Polypropylene in Relation to Dye Diffusion
Author(s) -
GARDNER K. L.,
McNALLY G. M.
Publication year - 1977
Publication title -
journal of the society of dyers and colourists
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.297
H-Index - 49
eISSN - 1478-4408
pISSN - 0037-9859
DOI - 10.1111/j.1478-4408.1977.tb03302.x
Subject(s) - polypropylene , spherulite (polymer physics) , polymer , polymer chemistry , diffusion , polar , saturation (graph theory) , materials science , morphology (biology) , extrusion , polymer science , chemical engineering , composite material , thermodynamics , mathematics , physics , geology , combinatorics , astronomy , engineering , paleontology
Diffusion coefficients of disperse dyes in polypropylene were found to be influenced by extrusion temperature and spherulite size. The assumption that sites in unmodified polypropylene do not exist is questioned. A correlation was observed between the number of polymer chain ends and saturation values for certain dyes and a polar interaction mechanism was proposed for such systems. The concept of fixing dye in the polymer by crystallizing the polymer was examined and found to be possible.