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THE ENVIRONMENTAL STABILITY OF ANCIENT CERAMICS
Author(s) -
FRANKLIN U. M.,
VITALI V.
Publication year - 1985
Publication title -
archaeometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.716
H-Index - 67
eISSN - 1475-4754
pISSN - 0003-813X
DOI - 10.1111/j.1475-4754.1985.tb00343.x
Subject(s) - ceramic , composition (language) , corrosion , mineralogy , chemical composition , materials science , chemistry , chemical engineering , metallurgy , organic chemistry , art , literature , engineering
A series of corrosion experiments was carried out using identical samples of a ceramic of known composition, structure and density which were subjected to a variety of simulated soil solutions. The action of the solutions was monitored by measuring their pH as a function of time at 25 °C and 90 °C. Under all conditions the pH stabilized rapidly. Microscopic and electron microscopic studies showed the presence of reaction/alteration products that would account for the observed pH changes. The findings indicate that ancient ceramics that exhibit no physical deterioration will have below their surface a composition corresponding to the composition of the sherd at the time of its burial.