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Seasonal variation of pyrite oxidation rates in colliery spoil
Author(s) -
Backes C. A.,
Pulford I. D.,
Duncan H. J.
Publication year - 1993
Publication title -
soil use and management
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.709
H-Index - 81
eISSN - 1475-2743
pISSN - 0266-0032
DOI - 10.1111/j.1475-2743.1993.tb00924.x
Subject(s) - pyrite , lysimeter , chemistry , environmental chemistry , coal , dissolution , mineralogy , environmental science , soil water , soil science , organic chemistry
. Oxidation rates of pyrite in colliery spoil were measured under both field and laboratory conditions. Meld oxidation rates varied through the year, depending primarily upon temperature. Rates of acid release of 7–15 μmoles H + /day were measured in field lysimeters in the period May to November. Little oxidation of the pyrite occurred between November and May; the rates in the summer months were approximately 5–10 times those during die winter. The rate of oxidation in the summer was limited by the solubility of amorphous iron oxides. Slow oxidation during the winter is probably related to the inactivity of Thiobacillus ferrooxidans at low temperatures. The rates of acid production in the laboratory in the temperature range 0–18°C were similar to those in the field. Materials inhibiting pyrite oxidation should be added when oxidation rates are slow, so that they are not overwhelmed by large amounts of acid.