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OBSERVATIONS ON THE RELATIONSHIP BETWEEN THE ADSORPTION OF DIURON AND THE NATURE OF THE ADSORBENT
Author(s) -
HANCE R. J.
Publication year - 1965
Publication title -
weed research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.693
H-Index - 74
eISSN - 1365-3180
pISSN - 0043-1737
DOI - 10.1111/j.1365-3180.1965.tb00333.x
Subject(s) - adsorption , chemistry , organic matter , aqueous solution , environmental chemistry , fraction (chemistry) , inorganic chemistry , organic chemistry
Summary. A series of adsorption experiments was carried out in order to determine if there was significant competition for adsorption sites between diuron and water. Adsorption of diuron was much lower on hydrophilic materials such as cellulose, chitin, aluminium oxide and a soil mineral fraction than on the less hydrophilic ion exchange resins, lignin, carbon and a soil organic fraction. Methylation with methanolic HCL or diazomethane increased adsorption by the soil organic material, but methylation with dimethyl sulphate did not. The soil mineral fraction adsorbed considerably more diuron from petroleum spirit solution than from aqueous solution, but the organic matter preparation adsorbed more from aqueous than from petroleum solution. It was concluded that there is competition between water and diuron for adsorption sites and that diuron is a more effective competitor at soil organic matter surfaces than at soil mineral matter surfaces. Observations sur la relation entre l'adsorption du diuron el la nature de l'adsorbant