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δ13C signature of early graphite and subsequently formed microdiamond from the Saxonian Erzgebirge, Germany
Author(s) -
Massonne HansJoachim,
Tu Wenmao
Publication year - 2007
Publication title -
terra nova
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.353
H-Index - 89
eISSN - 1365-3121
pISSN - 0954-4879
DOI - 10.1111/j.1365-3121.2007.00774.x
Subject(s) - zircon , geology , graphite , metamorphism , protolith , geochemistry , devonian , diamond , mineralogy , materials science , composite material
Microdiamond and graphite occur in quartzofeldspathic rocks (saidenbachites) of the central Erzgebirge in Saxony. Zircon from such rocks contains not only relatively high but also variable amounts of early formed graphite and later crystallized diamond, however no carbonate. Six purified zircon concentrates were analysed by mass spectrometry for δ 13 C(PDB) values which were between −24 and −33‰. The carbon inclusions resulted in C contents of the concentrates as high as 0.5 wt%. It is hypothesized that the observed δ 13 C signature results from organic material in the sedimentary protoliths of the saidenbachites probably deposited not earlier than Mid‐Devonian. This material was transformed to graphite during early metamorphism and subsequently to diamond after an anatectic event at great depths (>150 km). During these processes, the δ 13 C signature of the carbon did not (significantly) change.