TEM studies of plasma nitrided austenitic stainless steel

Summary Cross‐sectional transmission electron microscopy and X‐ray phase analysis were used to study the structure of a layer formed during nitriding the AISI 316L stainless steel at temperature 440°C. It was found that the applied treatment led to the formation of 6‐μm‐thick layer of the S‐phase. There is no evidence of CrN precipitation. The X‐ray diffraction experiments proved that the occurred austenite lattice expansion – due to nitrogen atoms – depended on the crystallographic direction. The cross‐sectional transmission electron microscopy studies showed that the layer consisted of a single cubic phase that contained a lot of defects such as dislocations, stacking faults, slip bands and twins. The high‐resolution electron microscopy observations were applied to study the defect formation due to the nitriding process. It was shown that the presence of great number of stacking faults leads to formation of nanotwins. Weak, forbidden {100} reflections were still another characteristic feature of the S‐phase. These were not detected in the X‐ray spectra of the phase. Basing on the high‐resolution electron microscopy studies it can be suggested that the short‐range ordering of the nitrogen atoms in the octahedral sites inside the f.c.c. matrix lattice takes place and gives rise to appearance of these spots. It is suggested that the cubic lattice undergoes not only expansion but also slight rombohedral distortion that explains differences in the lattice expansion for different crystallographic directions.