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The structure of 1D CuI crystals inside SWNTs
Author(s) -
KISELEV N.A.,
ZAKALYUKIN R.M.,
ZHIGALINA O.M.,
GROBERT N.,
KUMSKOV A.S.,
GRIGORIEV YU. V.,
CHERNYSHEVA M.V.,
ELISEEV A.A.,
KRESTININ A.V.,
TRETYAKOV YU.D.,
FREITAG B.,
HUTCHISON J.L.
Publication year - 2008
Publication title -
journal of microscopy
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.569
H-Index - 111
eISSN - 1365-2818
pISSN - 0022-2720
DOI - 10.1111/j.1365-2818.2008.02104.x
Subject(s) - transmission electron microscopy , crystallography , hexagonal crystal system , resolution (logic) , materials science , image contrast , electron microscope , copper , crystal structure , molecular physics , chemistry , nanotechnology , optics , physics , artificial intelligence , computer science , metallurgy
Summary Nanocomposites consisting of one‐dimensional CuI crystals inside single‐walled carbon nanotubes were obtained using the capillary technique. high‐resolution transmission electron microscopy investigations of the atomic structure of the encapsulated 1D CuI crystals revealed two types of 1D CuI crystals with growth direction <001> and relative to the bulk hexagonal CuI structure. Atomic structure models were proposed based on the high‐resolution transmission electron microscopy images. According to the proposed models and image simulations, the main contrast in the 1D crystal images arises from the iodine atoms whereas copper atoms, with lower atomic number giving lower contrast, are thought to be statistically distributed.