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REACTIONS OF SOLUBLE PHOSPHATE WITH ACID SOILS: THE INTERPRETATION OF ADSORPTION‐DESORPTION ISOTHERMS
Author(s) -
WHITE R. E.,
TAYLOR A. W.
Publication year - 1977
Publication title -
journal of soil science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.244
H-Index - 111
eISSN - 1365-2389
pISSN - 0022-4588
DOI - 10.1111/j.1365-2389.1977.tb02240.x
Subject(s) - gibbsite , desorption , adsorption , soil water , chemistry , phosphate , kaolinite , ionic strength , clay minerals , inorganic chemistry , cation exchange capacity , environmental chemistry , mineralogy , geology , soil science , aqueous solution , organic chemistry
Summary Adsorption‐desorption and isotopic‐exchange isotherms for acids soils of known clay mineralogy indicated that when all the surfaœ P accessible to the solution was considered, the bonding energy for phosphate decreased exponentially with site coverage. The soils differed markedly in the quantities of surface P held at sites of very high bonding energy, defined as those in equilibrium with a solution concentration < 1 μM; the values ranging from 9 μmol g −1 in a soil with 40 per cent gibbsite in the clay fraction, to 1 μmol g −1 in a soil with only 1 per cent gibbsite and no interlayered material. The reversibility of current P adsorption on soil surfaces depended on the immediate history of the soil sample. Complete reversibility occurred when soil, previously enriched with soluble P and stored for 4 to 5 months at constant temperature, was suspended in solutions of constant pH and ionic strength. It is suggested that irreversibility occurs due to incomplete attainment of equilibrium during the adsorption phase, a condition predisposed by high initial P concentrations (>1mM), and the use of soils that are naturally in dis‐equilibrium because of recent fertilizer additions or severe depletion of P by plant uptake.