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Atomic Structures and Energies of Σ7 Symmetrical Tilt Grain Boundaries in Alumina Bicrystals
Author(s) -
Nishimura Hitoshi,
Matsunaga Katsuyuki,
Saito Tomohiro,
Yamamoto Takahisa,
Ikuhara Yuichi
Publication year - 2003
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.2003.tb03343.x
Subject(s) - grain boundary , high resolution transmission electron microscopy , materials science , tilt (camera) , transmission electron microscopy , crystallography , condensed matter physics , plane (geometry) , boundary (topology) , lattice (music) , geometry , microstructure , composite material , chemistry , nanotechnology , physics , mathematical analysis , mathematics , acoustics
Symmetrical Σ7 tilt grain boundaries of alumina (Al 2 O 3 ) were studied using bicrystals. Three types of Σ7 boundaries were successfully fabricated, that is, rhombohedral twin (Σ7{1[Onemacr]02}) and two types of [0001] symmetrical tilt grain boundaries with grain‐boundary planes {4[Fivemacr]10} and {2[Threemacr]10} (Σ7{4[Fivemacr]10} and Σ7{2[Threemacr]10}). Their atomic structures and grain‐boundary energies were investigated using high‐resolution transmission electron microscopy (HRTEM) and a thermal grooving technique, respectively. HRTEM observations showed that the Σ7{1[Onemacr]02} boundary had a completely symmetrical atomic arrangement with respect to the grain‐boundary plane. In contrast, Σ7{2[Threemacr]10} and Σ7{4[Fivemacr]10} boundaries exhibited asymmetrical atomic structures, which were confirmed by analyzing the atomic configurations using static lattice calculations. Thermal grooving experiments showed that the grain‐boundary energies strongly depended on the properties of the grain‐boundary planes.