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Crystallographic Facetting in Sintered Barium Titanate
Author(s) -
Liou JingKai,
Lin MingHong,
Lu HongYang
Publication year - 2002
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.2002.tb00558.x
Subject(s) - faceting , materials science , microstructure , annealing (glass) , transmission electron microscopy , grain boundary , grain growth , crystallography , surface energy , barium titanate , scanning electron microscope , abnormal grain growth , mineralogy , composite material , nanotechnology , chemistry , ceramic
A commercial TiO 2 ‐excess BaTiO 3 powder has been sintered and its microstructure analyzed for crystallographic facetting via both scanning and transmission electron microscopy (SEM and TEM). Facetted grain surfaces are developed initially from {111} at a low temperature of 1215°C, which are then altered to {111} and {100} at 1290°C in the presence of a grain‐boundary liquid phase. The grain shape is also modified correspondingly from platelike to polygonal. Facetting of the intragranularly located residual pores in BaTiO 3 along the {141} planes further develops on the (quasi‐)equilibrium shape after annealing at 1400°C for 100 h from the initially well‐characterized {111}, {110}, and {100} in as‐sintered samples sintered at the same temperature for 10 h. The Wulff plots derived from the residual pores in as‐sintered and annealed samples are constructed for the 〈011〉 zone. Microstructural analysis also suggests that the shape of grains and intragranular residual pores is modified progressively upon annealing. The initial solid–vapor surface energy has become less anisotropic crystallographically. Abnormal grain growth in relation to the surface energy anisotropy is discussed.