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Synthesis of Platinum/Silica Nanocomposite Particles by Reverse Micelle and Sol–Gel Processing
Author(s) -
Bae DongSik,
Han KyongSop,
Adair James H.
Publication year - 2002
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.2002.tb00270.x
Subject(s) - microemulsion , alkoxide , micelle , sol gel , materials science , nanocomposite , chemical engineering , hydrolysis , pulmonary surfactant , particle size , condensation , molar ratio , platinum , nanoparticle , metal , inorganic chemistry , chemistry , organic chemistry , catalysis , nanotechnology , aqueous solution , metallurgy , physics , engineering , thermodynamics
Pt/SiO 2 nanosized particles have been synthesized using a reverse micelle technique combined with metal alkoxide hydrolysis and condensation. The size of the particles and the thickness of the coating can be controlled by manipulating the relative rates of the hydrolysis and condensation reactions of tetraethoxysilane (TEOS) within the microemulsion. The average size of synthesized particles was in the size range of 21–42 nm. The effects of synthesis parameters, such as the molar ratio of water to TEOS and the molar ratio of water to surfactant, are discussed.