Premium
Behavior of Paramagnetic Iron during the Thermal Transformations of Kaolinite
Author(s) -
Djemai Amédée,
Balan Etienne,
Morin Guillaume,
Hernandez Giancarlo,
Labbe Jean Claude,
Muller Jean Pierre
Publication year - 2001
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.2001.tb00784.x
Subject(s) - mullite , superparamagnetism , paramagnetism , electron paramagnetic resonance , ion , materials science , kaolinite , diffusion , goethite , inorganic chemistry , iron oxide , analytical chemistry (journal) , chemistry , metallurgy , adsorption , nuclear magnetic resonance , ceramic , thermodynamics , magnetization , condensed matter physics , physics , organic chemistry , quantum mechanics , chromatography , magnetic field
Kaolinites with various degrees of structural order and iron content were heated and subsequently analyzed via electron paramagnetic resonance. Iron was present in two different states in the heated materials, either as dilute structural Fe 3+ ions or in concentrated Fe 3+ phases. During metakaolinization, the environment of dilute Fe 3+ ions changed, following modifications of the Al 3+ coordination, and the Fe 3+ concentration increased. With the breakdown of metakaolinite, the diffusion of Fe 3+ ions induced their exsolution in superparamagnetic iron‐rich domains (Fe 3+ clusters in γ‐Al 2 O 3 and/or Fe 3+ oxide nanophases), which produced a decrease in the dilute Fe 3+ concentration. The subsequent breakdown of γ‐Al 2 O 3 and the formation of mullite made the dilute Fe 3+ concentration increase again, because of the incorporation of Fe 3+ ions in the mullite structure.