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Chloride‐Ion Activities in Simplified Synthetic Concrete Pore Solutions: The Effect of the Accompanying Ions
Author(s) -
Vera Guillem,
Hidalgo Ana,
Climent Miguel Angel,
Andrade Carmen,
Alonso Cruz
Publication year - 2000
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.2000.tb01245.x
Subject(s) - electrolyte , ion , chloride , ionic bonding , work (physics) , activity coefficient , chemistry , inorganic chemistry , thermodynamics , electrode , materials science , organic chemistry , physics , aqueous solution
Concrete pore solutions are concentrated electrolytes in which the activity of the chemical species must be calculated properly to determine the equilibrium state of such solutions. In this work, the chloride‐ion activity coefficients in synthetic concrete pore solutions have been obtained potentiometrically, using different calibrated Cl − ion‐selective electrodes (ISEs); also, a discussion about the performance of the different Cl − ISEs in alkaline media is presented. Experimental results are compared with the calculated results, using Pitzer's specific ionic‐interaction model, and good agreement is observed between them.