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Granularity and Surface Structure of Ground Granulated Blast‐Furnace Slags
Author(s) -
Tsuyuki Naomitsu,
Koizumi Koshiro
Publication year - 1999
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1999.tb02061.x
Subject(s) - ground granulated blast furnace slag , slag (welding) , reactivity (psychology) , silicate , fineness , materials science , blast furnace , granularity , mineralogy , metallurgy , chemical engineering , chemistry , cement , medicine , alternative medicine , pathology , computer science , engineering , operating system
Ground granulated blast‐furnace slags (GGBS) show improved hydration reactivity when granularity fineness increases, but the reason for the improvement in reactivity is still unknown. GGBS specimens with Blaine surface areas of 4680, 6470, and 8050 are analyzed, but the conventional reactivity criteria, such as degree of vitrification, basicity, and mineralogical composition, of the GGBS show no significant differences. X‐ray photoelectron spectroscopic analysis, however, successfully distinguishes and identifies SiO 2 gels as well as glassy phases of CaO‐SiO 2 and Al 2 O 3 ‐SiO 2 in the slag surfaces, where, with an increase in the Blaine surface area of the slag, CaO‐SiO 2 ‐type glass becomes dominant and contributes to the evolution of hydration, determined in terms of silicate anion morphology by the trimethylsilylation (TMS) method.