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Spin Coating of a Ca(Ti,Fe)O 3 Dense Film on a Porous Substrate for Electrochemical Permeation of Oxygen
Author(s) -
Itoh Hideaki,
Asano Hiroshi,
Fukuroi Keika,
Nagata Makoto,
Iwahara Hiroyasu
Publication year - 1997
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1997.tb02992.x
Subject(s) - materials science , sintering , calcination , permeation , substrate (aquarium) , chemical engineering , spin coating , oxygen , coating , porosity , composite material , membrane , chemistry , biochemistry , oceanography , organic chemistry , engineering , geology , catalysis
A dense Ca(Ti 0.75 Fe 0.25 )O 3−α (Ca(Ti,Fe)O 3 ) film, which is a mixed conductor of oxide ions and electrons/holes, was prepared on a porous CaTiO 3 substrate by a spin‐coating method. The calcined Ca(Ti,Fe)O 3 powder with 2–3 μm grain sizes was mixed with a dispersant in ethanol to form the slurry for spin coating. A uniform Ca(Ti,Fe)O 3 green film was obtained at 1000–1500 rpm on the rotating porous CaTiO 3 substrate, which had an average pore diameter of a few micrometers. The optimum sintering conditions for the spin‐coated films were a soaking temperature of 1235°C and a holding time of 2 h, in air. A dense, sintered Ca(Ti,Fe)O 3 film }20–50 μm thick was prepared by repeating the coatingsintering process. The gas‐tight film prepared on the porous substrate exhibited higher electrochemical permeation of oxygen at an operating temperature of 1000°C compared with that of thicker, sintered Ca(Ti,Fe)O 3 disks.
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