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SHS Combustion Characteristics of Several Ceramics and Intermetallic Compounds
Author(s) -
Makino Atsushi,
Law Chung K.
Publication year - 1994
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1994.tb05365.x
Subject(s) - materials science , intermetallic , nial , combustion , melting point , self propagating high temperature synthesis , ceramic , nonmetal , particle (ecology) , thermodynamics , thermal diffusivity , diffusion , particle size , oxide , composite material , metallurgy , metal , chemical engineering , microstructure , chemistry , oceanography , physics , engineering , alloy , geology
Extensive comparisons have been conducted between experimental and theoretical results for the SHS combustion characteristics of a number of solid‐solid systems. The heterogeneous flame propagation theory describes a premixed mode of bulk flame propagation supported by the nonpremixed reaction of dispersed nonmetal (or higher melting point metal) particles in the liquid metal, with finite‐rate reaction at the particle surface and temperature‐sensitive Arrhenius‐type condensed‐phase mass diffusivity. Systems examined are those of borides (TiB 2 , ZrB 2 , and HfB 2 ) and intermetallic compounds (NiAl, TiCo, and TiNi). By using a consistent set of physico‐chemical parameters for these systems, satisfactorily quantitative agreement is demonstrated for the effects of mixture ratio, degree of dilution, and particle size on the burning velocity. Experimental flammability limits are also predicted by the theory.