Premium
Structural Evolution of Colloidal Silica Gels to Glass
Author(s) -
Ying Jackie Y.,
Benziger Jay B.,
Navrotsky Alexandra
Publication year - 1993
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1993.tb03982.x
Subject(s) - cristobalite , colloidal silica , crystallization , materials science , colloid , chemical engineering , sintering , sol gel , ceramic , differential scanning calorimetry , thermal analysis , mineralogy , chemistry , composite material , thermal , nanotechnology , quartz , physics , meteorology , engineering , thermodynamics , coating
The gel‐to‐ceramic evolution of colloidal‐derived silica gels was examined by thermal analysis, infrared photoacoustic spectroscopy, physical characterization, and high‐temperature calorimetry. Oxygen in the firing atmosphere promoted sintering of colloidal gels relative to firing in a nitrogen or argon atmosphere. Water vapor in the atmosphere promoted consolidation and crystallization to cristobalite. Addition of PVA to the colloidal gel resulted in consolidation and crystallization of the gel at 1000°C, ∼150°C less than gels without the PVA binder. The enthalpy of consolidation of the gels to fused silica glass was approximately − 10 kJ/mol, primarily due to reduction of surface area.