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Interplay of Sintering Microstructures, Driving Forces, and Mass Transport Mechanisms
Author(s) -
Can Rowland M.,
Carter W. Craig
Publication year - 1989
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1989.tb07705.x
Subject(s) - sintering , dihedral angle , surface diffusion , materials science , diffusion , microstructure , shrinkage , mass transport , surface (topology) , function (biology) , mechanics , thermodynamics , chemistry , composite material , geometry , physics , mathematics , engineering physics , hydrogen bond , organic chemistry , adsorption , evolutionary biology , molecule , biology
The equilibrium shapes of segments of a row of sintering particles are calculated for the case where interparticle distances are constrained and, in particular, for only vapor‐phase transport or surface diffusion active. These equilibrium states are contrasted with those obtained by mechanisms which allow densification. The sintering potentials and surface curvatures are calculated for the equilibrium shapes as a function of dihedral angle. Expressions for the rate of shrinkage are presented and, for the case of equilibrium structures, calculated exactly.

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