Premium
Li‐(Mg,Zn,Ni) Vanadates
Author(s) -
CHANG LUKE L. Y.,
WANG F. Y.
Publication year - 1988
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1988.tb06389.x
Subject(s) - solid solution , spinel , ternary numeral system , chemistry , inorganic chemistry , phase (matter) , ternary operation , mineralogy , crystallography , analytical chemistry (journal) , materials science , metallurgy , organic chemistry , computer science , programming language , chromatography
Phase relations were determined in the systems of Li‐(Mg,Zn,Ni) vanadates in the temperature range between 500° and 800°C. Each of the ternary systems Li 2 O‐(Mg, Zn, or Ni)O‐V 2 O 5 is characterized by an orthovanadate: olivine‐type LiMgVO 4 , phenakite‐type LiZnVO 4 , and spinel‐type LiNiVO 4 . Mutual solid solutions form between them. Two solid solutions, a large region of the NiV 2 O 6 type and a complete series between MgV 2 O 6 and ZnV 2 O 6 , exist in the system (Mg,Zn,Ni)V 2 O 6 . The system (Mg,Zn,Ni) 2 V 2 O 7 has an extensive solid‐solution region based on Ni 2 V 2 O 7 , whereas the system (Mg,Zn,Ni) 3 V 2 O 8 is characterized by a complete series.