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Quantitative Determination of the Deuteroxyl Content of Vitreous Silica
Author(s) -
Shelby James E.
Publication year - 1987
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1987.tb04858.x
Subject(s) - molar absorptivity , deuterium , chemistry , materials science , analytical chemistry (journal) , chromatography , optics , physics , quantum mechanics
The deuteroxyl absorptivity for vitreous silica was determined by measurement of the reaction of hydrogen and deuterium with a form of vitreous silica known to form a specific amount of hydroxyl under all experimental conditions. The deuteroxyl absorptivity was found to be 90.4% of that of hydroxyl, or 164 L /(mol·cm).