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Effect of Chloride Incorporation on the Crystallization of Zirconium‐Barium‐lanthanum‐Aluminum Fluoride Glass
Author(s) -
NEILSON GEORGE F.,
SMITH GARY L.,
WEINBERG MICHAEL C.
Publication year - 1985
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1985.tb16166.x
Subject(s) - lanthanum , crystallization , zirconium , fluoride , barium , chlorine , inorganic chemistry , aluminium , materials science , chloride , nuclear chemistry , chemistry , metallurgy , organic chemistry
One aspect of the influence of preparation procedure on the crystallization behavior of a zirconium‐barium‐lanthanum‐aluminum fluoride glass was studied. The crystallization pattern of this glass may be affected by the chlorine concentration within it. In particular, when such glasses are heated at low temperatures, the α‐BaZrF 6 crystalline phase forms only in those glasses which contain chloride.