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Electrical Conductivity of Alkali‐Doped Zr‐Ba‐La‐Al Fluoride Glasses
Author(s) -
SHELBY JAMES E.
Publication year - 1985
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1985.tb10165.x
Subject(s) - alkali metal , fluoride , electrical resistivity and conductivity , doping , conductivity , materials science , inorganic chemistry , ion , mineralogy , analytical chemistry (journal) , oxide , chemistry , metallurgy , optoelectronics , organic chemistry , chromatography , electrical engineering , engineering
The effect of alkali ion identity on the dc electrical conductivity of alkali‐doped Zr‐Ba‐La‐Al fluoride glasses containing 5 mol% MF, where M is Li, K, or Cs, was measured. The electrical conductivity increases in the order Li < K < Cs. This trend is the reverse of that found for typical oxide glasses. Results support the contention that these glasses are anion conductors.