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Nitrogen Coordination in Oxynitride Glasses
Author(s) -
Brow RichardK.,
Pantano CarloG.,
Boyd D.C.
Publication year - 1984
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1984.tb18834.x
Subject(s) - x ray photoelectron spectroscopy , nitrogen , soda lime , fourier transform infrared spectroscopy , spectroscopy , materials science , mineralogy , infrared spectroscopy , silica glass , lime , analytical chemistry (journal) , chemical engineering , chemistry , metallurgy , environmental chemistry , composite material , organic chemistry , physics , quantum mechanics , engineering
Soda‐silica and soda‐lime‐silica glasses were prepared with varying amounts of Si 3 N 4 , to produce oxynitride glasses with nitrogen contents up to 3.23 mol%. The glasses were analyzed by Fourier transform infrared spectroscopy and X‐ray photoelectron spectroscopy, and evidence for the formation of tricoordinated nitrogen groups in the glasses was obtained.