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Computation of Ternary Molten Salt Phase Diagrams
Author(s) -
LIN P.L.,
PELTON A. D.,
BALE C. W.
Publication year - 1979
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1979.tb19091.x
Subject(s) - ternary operation , phase diagram , thermodynamics , binary number , ternary plot , ternary numeral system , molten salt , phase (matter) , interpolation (computer graphics) , calphad , computation , materials science , chemistry , computer science , mathematics , physics , algorithm , organic chemistry , animation , computer graphics (images) , arithmetic , programming language
The thermodynamic properties of all phases in the 15 binary systems formed among the salts LiCl, NaCl, KCI, MgCl 2 , CaCl 2 , and SrCl 2 , were obtained and expressed in mathematical form by a critical analysis of the measured binary phase diagrams and of published binary thermodynamic data. Interpolation procedures were then used to estimate the thermodynamic properties of the 20 ternary systems formed among the 6 salts and all 20 ternary phase diagrams were calculated using a computer program designed for the purpose. Agreement with the measured phase diagrams for the 8 ternary systems for which measured diagrams are available is good.