Premium
Solubility Limits in Binary (Ca,Mn) Chalcogenides
Author(s) -
LEUNG CHIHUNG,
VLACK LAWRENCE H.
Publication year - 1979
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1979.tb12743.x
Subject(s) - liquidus , eutectic system , solid solution , solubility , miscibility , solid solubility , spinodal decomposition , phase diagram , thermodynamics , binary number , materials science , mineralogy , chemistry , analytical chemistry (journal) , phase (matter) , microstructure , metallurgy , physics , chromatography , mathematics , organic chemistry , polymer , arithmetic , composite material
Solid solubilities progressively decrease in the systems CaS‐MnS, CaSe‐MnSe, and CaTe‐MnTe. In CaS‐MnS, full solid miscibility extends from 1150° to 1500°C, the liquidus minimum. With CaSe‐MnSe, this range is 1070° to 1340°C. The solid miscibility gap between CaTe and cubic MnTe intercepts the liquidus as a eutectic at 1050°C. The solid solutions follow Vegard's law closely.