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Migration Losses in Single‐Crystal Ionic Conductors: Sodium Beta Alumina and
Author(s) -
GRANT R. J.,
HODGE I. M.,
INGRAM M. D.,
WEST ANTHONY R.
Publication year - 1977
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1977.tb14111.x
Subject(s) - ionic conductivity , ionic bonding , electrical conductor , conductivity , ion , materials science , single crystal , electrical resistivity and conductivity , crystal (programming language) , mineralogy , sodium , chemical physics , modulus , chemical engineering , crystallography , composite material , chemistry , metallurgy , physics , engineering , organic chemistry , electrode , quantum mechanics , computer science , programming language , electrolyte
Dispersions have been observed in the ac conductivity of 2 single‐crystal ionic conductors, Na β ‐alumina and LiGaO 2 . The results have been analyzed in the complex modulus formalism, M °, where M °= (ε°) −1 . It is suggested that these dispersions represent conductivity losses and are similar to those observed in glasses. The losses are related to the mechanism of ion migration and may be a characteristic feature of many ionically conducting crystalline materials.

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