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Creep of Polycrystalline MgO and MgO‐Fe 2 O 3 Solid Solutions at High Temperatures
Author(s) -
TERWILLIGER G. R.,
BOWEN H. K.,
GORDON R. S.
Publication year - 1970
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1970.tb12085.x
Subject(s) - creep , materials science , crystallite , grain boundary , dislocation , grain size , hot pressing , grain boundary diffusion coefficient , composite material , strain rate , grain growth , diffusion , thermodynamics , metallurgy , analytical chemistry (journal) , mineralogy , microstructure , chemistry , physics , chromatography
Polycrystalline MgO and MgO‐Fe 2 O 3 solid solutions (0.10 to 8.08 wt% Fe 2 O 3 ) were fabricated to almost theoretical density by vacuum hot‐pressing. Specimens were creep‐tested in air under four‐point dead‐load conditions between 1000° and 1400°C at stresses between 50 and 550 kg/cm 2 . Steady‐state creep was never achieved in the experiments, which sometimes lasted more than 50 h. The strain rate vs time ( t ) data were described by an equation of the form = c 1 /(t+C 2 ) p , which is consistent with the assumptions that creep occurs at least in part by a “viscous” mechanism and that grain growth occurs simultaneously. Doping MgO with Fe 2 O 3 enhanced the viscous contributions to creep and inhibited the nonviscous ones. Creep rates in these specimens increased with increasing Fe 2 O 3 additions. The occurrence of simultaneous grain growth during the high‐temperature creep of magnesiowustite (i.e. MgO‐Fe 2 O 3 solid solutions) was used in establishing the strain rate vs grain size dependence. The results of this study are consistent with a transition between grain boundary and lattice diffusion mechanisms as the grain size increases (4 to 44 μan). The creep of polycrystalline MgO is a mixed process in that viscous and nonviscous (dislocation) contributions are present.