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Solubilities of Ar, N 2 , CO 2 , and He in Glasses at Pressures to 10 Kbars
Author(s) -
FAILE S. P.,
ROY DELLA M.
Publication year - 1966
Publication title -
journal of the american ceramic society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.9
H-Index - 196
eISSN - 1551-2916
pISSN - 0002-7820
DOI - 10.1111/j.1151-2916.1966.tb13190.x
Subject(s) - analytical chemistry (journal) , ambient pressure , solubility , atmospheric pressure , materials science , mineralogy , chemical composition , chemistry , thermodynamics , environmental chemistry , geology , organic chemistry , physics , oceanography
Glasses containing up to several percent of Ar, N 2 , and CO 2 were prepared at 2000 to 150,000 psi and up to 950°C and retained under ambient conditions. The solubilities are presented as a function of pressure, temperature, and composition of glass. Solubilities of O, He, and H 2 O were also investigated in various glass compositions, especially K 2 O–4SiO 2 and B 2 O 3 . The evolution of the gases at atmospheric pressure was followed by electron microscopy and density measurements.